1,1-Dibenzyl-3-(3-chlorobenzoyl)thiourea

1,1-Dibenzyl-3-(3-chloro­benzo­yl)thio­urea

In the title compound, C(22)H(19)ClN(2)OS, the thiono and carbonyl groups are trans positioned with respect to a partially double C-N bond. The amide group is twisted relative to the thio-urea fragment, forming a dihedral angle of 46.75 (11)°. In the crystal, inter-molecular N-H⋯S and C-H⋯O hydrogen bonds link the mol-ecules into a one-dimensional polymeric structure parallel to the c axis.

1,1-Dibenzyl-3-(4-fluoro­benzo­yl)thio­urea

In the title compound, C(22)H(19)FN(2)OS, the 2-fluoro-benzoyl group adopts a trans conformation with respect to the thiono S atom across the N-C bond. In the crystal, inter-molecular N-H⋯S, C-H⋯S and C-H⋯O hydrogen bonds link the mol-ecules, forming a two-dimensional network parallel to (101).

1 , 8 - bis ( 2 - hydroxy - 3 , 5 - di - tert - butylbenzyl ) - 4 , 11 - dibenzyl - 1 , 4 , 8 , 11 - tetraazacyclotetradecane

A cyclam (1,4,8,11-tetraazacyclotetradecane)-based macrocycle bearing two benzyl and two 2-hydroxy-3,5-di-tert-butylbenzyl pendent arms was synthesized and characterized using spectroscopic techniques and single crystal X-ray diffraction. The macrocycle crystallizes in the triclinic space group P-1, with the asymmetric unit containing one-half of the molecule. The structure is stabilized by hyd...

Cover vol. 11, no. 3, June 2014

3-Allyl-1,5-dibenzyl-1,5-benzodiazepine-2,4-dione

The title compound, C(26)H(24)N(2)O(2), features a benzene ring fused with a seven-membered diazepine ring; the latter ring adopts a boat conformation (with the allyl-dimethyl-amino-methyl-bearing C atom as the prow and the fused-ring C atoms as the stern).